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Novel Nanoscale Hybrid Materials

Novel Nanoscale Hybrid Materials

Authors
Publisher Blackwell Science
Year 01/02/2018
Edition First
Pages 368
Version hardback
Readership level Professional and scholarly
Language English
ISBN 9781119156246
Categories Nanotechnology, Materials science
$186.20 (with VAT)
726.38 PLN / €169.26 / £144.90
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Book description

A comprehensive and interdisciplinary resource filled with strategic insights, tools, and techniques for the design and construction of hybrid materials. Hybrid materials represent the best of material properties being combined for the development for materials with properties otherwise unavailable for application requirements. Novel Nanoscale Hybrid Materials is a comprehensive resource that contains contributions from a wide range of noted scientists from various fields, working on the hybridization of nanomolecules in order to generate new materials with superior properties. The book focuses on the new directions and developments in design and application of new materials, incorporating organic/inorganic polymers, biopolymers, and nanoarchitecture approaches. This book delves deeply into the complexities that arise when characteristics of a molecule change on the nanoscale, overriding the properties of the individual nanomolecules and generating new properties and capabilities altogether. The main topics cover hybrids of carbon nanotubes and metal nanoparticles, semiconductor polymer/biopolymer hybrids, metal biopolymer hybrids, bioorganic/inorganic hybrids, and much more. This important resource: Addresses a cutting-edge field within nanomaterials by presenting groundbreaking topics that address hybrid nanostructures Includes contributions from an interdisciplinary group of chemists, physicists, materials scientists, chemical and biomedical engineers Contains applications in a wide-range of fields--including biomedicine, energy, catalysis, green chemistry, graphene chemistry, and environmental science Offers expert commentaries that explore potential future avenues of future research trends Novel Nanoscale Hybrid Materials is an important resource for chemists, physicists, materials, chemical and biomedical engineers that offers the most recent developments and techniques in hybrid nanostructures.

Novel Nanoscale Hybrid Materials

Table of contents

List of Contributors xiii


1 Silanols as Building Blocks for Nanomaterials 1
Masafumi Unno and Hisayuki Endo


1.1 Introduction 1


1.2 Synthesis and Applications of Silanols 2


1.2.1 Silanetriols and Disiloxanetetraols 2


1.2.2 Cyclotetrasiloxanetetraol (Cyclic Silanols, All ]cis Isomer) 5


1.2.3 Cyclotetrasiloxanetetraol (Cyclic Silanols, Other Isomers) 14


1.2.4 Cyclotrisiloxanetriol 15


1.3 Structures and Properties of Nanomaterials Obtained from Silanols 20


1.3.1 Structure of Laddersiloxanes 20


1.3.2 Thermal Property of Laddersiloxanes 23


1.3.3 Thermal Property of Other Silsesquioxanes 26


1.3.4 Refractive Indices of Silsesquioxanes 28


1.4 Summary and Outlook 29


References 29


2 Biomacromolecule ]Enabled Synthesis of Inorganic Materials 33
Kristina L. Roth and Tijana Z. Grove


2.1 Introduction 33


2.2 DNA 34


2.3 Proteins and Peptides 36


2.3.1 Cage Proteins 37


2.3.2 Bovine Serum Albumin (BSA) 38


2.3.3 Engineered Peptides 40


2.3.4 Engineered Protein Scaffolds 42


2.4 Polysaccharides 44


2.5 Methods of Characterization 46


2.6 Conclusion 50


References 50


3 Multilayer Assemblies of Biopolymers: Synthesis, Properties, and Applications 57
Jun Chen, Veronika Kozlovskaya, Danielle Pretorius, and Eugenia Kharlampieva


3.1 Introduction 57


3.2 Assembly of Biopolymer Multilayers 58


3.2.1 Biopolymers and Their Properties 58


3.2.2 Growth and Thickness of Biopolymer Multilayers 59


3.2.3 Stability in Solutions and Enzymatic Degradation of Biopolymer Multilayers 74


3.2.3.1 Enzymatic Degradation 75


3.2.3.2 pH and Salt Stability 78


3.2.4 Hydration and Swelling of Biopolymer Multilayers 81


3.3 Properties of Biopolymer Multilayers 83


3.3.1 Surface Properties of Biopolymer Multilayers and Their Interaction with Cells 83


3.3.2 Antibacterial Properties 84


3.3.3 Immunomodulatory Properties 85


3.3.4 Mechanical Properties of Biopolymer Multilayers 87


3.3.5 Other Properties 90


3.4 Applications 91


3.5 Conclusion and Outlook 95


Acknowledgments 96


References 96


4 Functionalization of P3HT ]Based Hybrid Materials for Photovoltaic Applications 107
Michele Chevrier, Riccardo Di Ciuccio, Olivier Coulembier, Philippe Dubois, Sebastien Richeter, Ahmad Mehdi, and Sebastien Clement


4.1 Introduction 107


4.2 Design and Synthesis of Regioregular Poly(3 ]Hexylthiophene) 109


4.2.1 Metal ]Catalyzed Cross ]Coupling Reactions 114


4.2.1.1 Nickel ]Catalyzed Cross ]Coupling Reactions 114


4.2.1.2 Palladium ]Catalyzed Cross ]Coupling Reactions 121


4.2.2 Functionalization of P

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