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The Heaviest Metals

The Heaviest Metals

Autorzy
Wydawnictwo Blackwell Science
Data wydania 01/01/2019
Wydanie Pierwsze
Liczba stron 544
Forma publikacji książka w twardej oprawie
Poziom zaawansowania Dla profesjonalistów, specjalistów i badaczy naukowych
Język angielski
ISBN 9781119304098
Kategorie Chemia
862.00 PLN (z VAT)
$227.74 / €189.28 / £163.51 /
Produkt dostępny
Dostawa 2 dni
Ilość
Do schowka

Opis książki

An authoritative survey of the science and advanced technological uses of the actinide and transactinide metals The Heaviest Metals offers an essential resource that covers the fundamentals of the chemical and physical properties of the heaviest metals as well as the most recent advances in their science and technology. The authors - noted experts in the field - offer an authoritative review of the actinide and transactinide elements, i.e., the elements from actinium to lawrencium as well as rutherfordium through organesson, the current end of the periodic table, element 118. The text explores the history of the metals, their occurrence and issues of production, and covers a broad range of chemical subjects including environmental concerns and remediation approaches. The authors also offer information on the most recent and emerging applications of the metals, such as in superconducting materials, catalysis, and research into medical diagnostics. This important resource: Provides an overview of the science and advanced technological uses of the actinide and transactinide metals Describes the basic chemical and physical properties of the heaviest metals, and discusses the challenges and opportunities for their technological applications Contains accessible information on the fundamental features of the heaviest metals, special requirements for their experimental study, and the critical role of computational characterization of their compounds Highlights the most current and emerging applications in areas such as superconducting materials, catalysis, nuclear forensics, and medicine Presents vital contemporary issues of the heaviest metals Written for graduate students and researchers working with the actinide and transactinide elements, industrial and academic inorganic and nuclear chemists, and engineers, The Heaviest Metals is a comprehensive volume that explores the fundamental chemistry and properties of the heaviest metals, and the challenges and opportunities associated with their present and emerging technological uses.

The Heaviest Metals

Spis treści

Contributors xi


Series Preface xv


Volume Preface xvii


PART 1: BACKGROUND 1


Discovery of the Actinide and Transactinide Elements 3
Mary Virginia Orna and Marco Fontani


Production of Plutonium 31
David L. Clark and Franz J. Freibert


Controlling Actinide Extraction Chemistry (Separation of Actinides from Lanthanides as Part of Nuclear Fuel Recycling) 39
James Westwood and Laurence M. Harwood


PART 2: FUNDAMENTALS 57


Electronic Structure of the Actinide Elements 59
Frederic Gendron and Jochen Autschbach


Electronic Structure of the Transactinide Atoms 77
Ephraim Eliav, Anastasia Borschevsky and Uzi Kaldor


Chemical Properties of the Transactinide Elements 93
Christoph E. Dullmann


Multiple Bonding in Actinide Chemistry 105
Michael A. Boreen and John Arnold


Electronic Structure of Actinide Oxides 123
Lindsay E. Roy


PART 3: CHARACTERIZATION METHODS 143


Crystallography of Actinide Complexes 145
Brian L. Scott, Samantha K. Cary and Justin N. Cross


Solid State NMR of Actinide-Containing Compounds 177
G. Koutroulakis and H. Yasuoka


Moessbauer Spectroscopy of Actinide Compounds 185
iotr Gaczynski


Photoelectron Spectroscopy of Actinide Materials 193
Thomas Gouder and Rachel Eloirdi


Laser-Based Spectroscopic Studies of Actinide Complexes 209
Euo C. Jung, Hye-Ryun Cho, Hee-Kyung Kim and Wansik Cha


Ab Initio Electronic Structure Calculations for Actinide and Transactinide Atoms and Molecules 223
Michael Dolg and Xiaoyan Cao


PART 4: DISTINCTIVE CHEMISTRY 247


Divalent Actinides and Transactinides: Inorganic and Organometallic Complexes 249
Leonor Maria, Joaquim Marcalo and John K. Gibson


Organometallic Chemistry of Pentavalent Uranium 263
Jesse Murillo and Skye Fortier


Amido Complexes of the Actinides 283
avid J. H. Emslie


Actinide Pnictogen Complexes 301
Sean P. Vilanova and Justin R. Walensky


Actinide Borohydrides 319
Scott R. Daly


Supramolecular and Macrocyclic Chemistry of the Actinides 335
ei Mei, Jianhui Lan, Kongqiu Hu and Weiqun Shi


Actinide Polyoxometalates 355
Peter C. Burns


PART 5: ENVIRONMENTAL AND HEALTH ISSUES 365


Actinide Speciation and Bioavailability in Fresh and Marine Surface Waters 367
Scott J. Markich and Paul L. Brown


Transuranic Biogeochemistry 401
Hakim Boukhalfa and Mary Neu


Sustainable Remediation in Complex Geologic Systems 415
Haruko Wainwright, Bhavna Arora, Susan Hubbard, Konstantin Lipnikov, Greg Flach, David Moulton, Carol Eddy-Dilek and Miles Denham


Nuclear Forensics 427
Maria Wallenius, Klaus Lutzenkirchen, Klaus Mayer and Zsolt Varga


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