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Discover the physical chemistry of charge carriers in the second edition of this popular textbookIonic and electronic charge carriers are critical to the kinetic and electrochemical properties of ionic solids. These charge carriers are point defects and are decisive for electrical conductivity, mass transport and storage phenomena. Generally, defects are deviations from the perfect structure, and if higher-dimensional, also crucial for the mechanical properties. The study of materials science and energy research therefore requires a thorough understanding of defects, in particular the charged point defects, their mobilities and formation mechanisms.Physical Chemistry of Ionic Materials is a comprehensive introduction to these charge carrier particles and the processes that produce, move, and activate them. Covering both core principles and practical applications, it discusses subjects ranging from chemical bonding and thermodynamics to solid-state kinetics and electrochemical techniques. Now in an updated edition with numerous added features, it promises to be the essential textbook on this subject for a new generation of materials scientists.Readers of the 2nd Edition of Physical Chemistry of Ionic Materials will also find:* Two new chapters on solid state electrochemistry and another on nanoionics* Novel brief sections on photoelectrochemistry, bioelectrochemistry and atomistic modelling put the treatment into a broader context* Discussion of the working principles required to understanding electrochemical devices like sensors, batteries, and fuel cells* Real laboratory measurements to ground basic principles in practical experimentationPhysical Chemistry of Ionic Materials is a valuable reference for chemists, physicists, and any working researchers or advanced students in the materials sciences.

Physical Chemistry of Ionic Materials: Ions and Electrons in Solids

Chapter 1 - IntroductionChapter 2 - Bonding aspects: From atoms to solid stateChapter 3 - PhononsChapter 4 - Equilibrium thermodynamics of the perfect solidChapter 5 - Equilibrium thermodynamics of the real solidChapter 6 - Kinetics and irreversible thermodynamicsChapter 7 - Solid state electrochemistry I: Measurement techniquesChapter 8 - Solid state electrochemistry II: Applications and devicesChapter 9 - Nanoionics